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Chlorides

Stock No.
NS6130-12-001149
CAS
18618-55-8
MSDS
MSDS-PDF
Specifications
SPEC-PDF
COA
COA-PDF
Catalogue

Cerium Chloride Heptahydrate

(CeCl3•7(H2O)
Cerium Chloride Heptahydrate
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Preview
Particles Size Analysis - CeCl3•7(H2O) Powder
ProductCerium Chloride Heptahydrate
Stock NoNS6130-12-001149
CAS18618-55-8Confirm
Purity99.9%Confirm
APS80-100nmConfirm
Molecular FormulaCeCl3•7(H2O)Confirm
Molecular Weight372.58g/molConfirm
FormPowderConfirm
ColorWhite/Light YellowConfirm
Specific Gravity3.94g/cm³Confirm
Softening Temperature848°CConfirm
SolubilitySoluble in Alcohol, Water
Quality ControlEach Lot of was tested successfully
Main Inspect VerifierManager QC

Typical Chemical Analysis

Assay99.9%
Other Metal1000 ppm

Expert Reviews

product-expert-image
Dr. Bruce Perrault, Ph.D (Georgia Institute of Technology (Georgia Tech), USA)

Cerium chloride can be used as a starting point for the preparation of other cerium salts, such as the Lewis acid, cerium (III) trifluoromethanesulfonate, used for Friedel-Crafts acylations. It is also used itself as a Lewis acid, for example as a catalyst in Friedel-Crafts alkylation reactions. Luche reduction of alpha, beta-unsaturated carbonyl compounds has become a popular method in organic synthesis, where CeCl3·7H2O is used in conjunction with sodium borohydride.

product-expert-image
Dr. Myron Rubenstein, Ph.D (Polytechnic University of Turin, Italy)

Cerium (III) chloride (CeCl3), also known as cerous chloride or cerium trichloride, is a compound of cerium and chlorine. It is a white hygroscopic solid; it rapidly absorbs water on exposure to moist air to form a hydrate, which appears to be of variable composition, though the heptahydrate CeCl3·7H2O is known. It is highly soluble in water, and (when anhydrous) it is soluble in ethanol and acetone.

product-expert-image
Dr. Huojin Chan (University of Science and Technology of China, Hefei, Anhui, China)

Cerium shows +4 and +3 oxidation state. Cerium (IV) compounds were extensively used as convenient and effective one-electron oxidants for a variety of transformations. However, the most stable oxidation state of cerium is +3 and cerium chloride heptahydrate (CeCl3.7H2O) is the most common source of Ce+3. CeCl3.7H2O is a commercially Lanthanide reagent which is water tolerant, easy to handle and inexpensive.

product-expert-image
Dr. Ms. Yi Yen Shi (King Mongkut’s University of Technology Thonburi, Bangkok, Thailand)

Cerium (III) chloride has been used in organic synthesis. Due to this reason, the crucial oxophilic character of cerium (III) chloride is governing chemo-regio-, and stereoselectivity promoted transformations. Cerium chloride heptahydrate (CeCl3.7H2O) have received much attention due to its low toxicity energy saving, high purity delivering products, stability, green and efficient Lewis acid in modern organic synthesis.

product-expert-image
Dr. Hans Roelofs Ph.D  (National Technical University of Athens, Greece)

Cerium chloride heptahydrate is often used to prepare cerium oxide nanoparticles by various methods. In one such technique; it reacts with sodium-oleate to form a cerium-oleate complex which can be further decomposed in hydrocarbon solvents to prepare cerium oxide nanoparticles.

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Cerium Chloride Heptahydrate

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